Skip to content

PFAS

Introduction

PFAS, or Per- and Polyfluoroalkyl Substances, comprise a complex family of more than 10,000 synthetic chemicals that are widely used in everyday products due to their resistance to water, grease, and stains. These chemicals have been utilized for decades in a range of applications, including non-stick cookware, water-repellent fabrics, and firefighting foams.

Though highly valuable for these purposes, growing evidence points to potential health risks associated with PFAS exposure and their persistence in the environment. As they are commonly referred to as “forever chemicals,” due to their inability to break down naturally, concerns over their impact on both human health and the environment have led to increased scrutiny and regulation.

What are PFAS Chemicals?

  • Per and Poly Fluoroalkyl Substances
  • Group of over 10,000 fluorinated organic chemicals
  • Emerging Contaminant
  • Become engrained in almost everything we use

Where are PFAS Used?

Used to make products more heat resistant, stain-resistant, waterproof and/or nonstick as well as help reduce friction in certain products.
  • Fire-fighting foams
  • Fabric surface protectants
  • Upholstered furniture & carpets
  • Cleaning products
  • Pesticide formulations
  • Non-stick cookware
  • Electronic devices
  • Some food takeout containers
  • Paint & building materials
PFAS Cycle
Click image for detailed version

Potential Health Impacts

  • Reproductive effects
  • Developmental effects
  • Effects on the immune system (antibody production)
  • Increased risk of cancer
  • Increased cholesterol/risk of obesity

Accumulate and stay in the body.

Impacts can occur at fairly low concentrations.

Proposed Regulation

blank

The United States Environmental Protection Agency (EPA) has proposed the first ever drinking water regulations for six PFAS chemicals. The proposed rule sets a maximum contaminant level goal (MCLG) of zero and a maximum contaminant level (MCL) of 4.0 Parts per Trillion (ppt) for both PFOS and PFOA.

EPA also proposed a Hazard Index approach, as described below, toward the regulation of a mixture of four PFAS chemicals: PFHxS, HFPO-DA (GenX), PFNA, and PFBS. The proposed regulatory framework is based on running annual average of samples, which is similar to the compliance methodology for disinfection by-products.

Hazard Index

Health Based Water Concentration (HBWC)

Levels protective of health effects over a lifetime of exposure, including sensitive populations and life stages.

Hazard Quotient

Ratio of potential exposure to a substance and the level at which no health effects are expected (HBWC).

Hazard Index (HI)

Sum of component Hazard Quotients (HQs), which are calculated by dividing the measured regulated PFAS component contaminant concentration in water by the associated Health Based Water Concentration.

A hazard index calculation greater than 1.0 would trigger a violation and corresponding regulatory enforcement action.

blank
Hazard Index equation
Hazard Index equation
Hazard Index equation
Hazard Index equation

Treatment Technologies

Considerations for selecting a treatment solution:

• Space available

• Pretreatment requirements

• Removal effectiveness

• Capital investment

• Operating costs

• Disposal of waste/media

Granular Activated Carbon (GAC)

Removal Mechanism:
PFAS compounds absorb to the porous carbon particles
  • Most proven PFAS treatment technology
  • Removal effectiveness affected by other water quality parameters such as Total Organic Carbon (TOC)
  • GAC is typically a single use product and requires disposal once breakthrough has occurred
  • Less effective for some PFAS, such as short-chain
  • GAC regeneration and carbon disposal is a potential pollution concern
  • Regenerated GAC can not be utilized in drinking water
  • Relatively large equipment footprint

Ion Exchange (IX)

Removal Mechanism:
Positively charged resins/polymers bind the negatively charged PFAS (and other) compounds
  • Can be specialized for specific PFAS compounds
  • Most IX resins used for PFAS are single use media due to difficulties achieving effective regeneration
  • Other IX resins are being promoted as effective for onsite regeneration using proprietary regeneration processes
  • Proprietary resins and limited suppliers can increase costs
  • Reduced equipment footprint

Reverse Osmosis (RO)

Removal Mechanism:
Contaminated water is pressurized and forced through a semipermeable membrane that filters out PFAS (and other contaminants)
  • Best broad spectrum PFAS removal but most costly treatment solution
  • The PFAS is concentrated into a brine waste stream
  • Moderate equipment footprint
  • Increased energy and chemical costs
  • Disposal of waste brine stream can be difficult

Treatment Residuals Issues

PFAS accumulating in treatment residuals also presents challenges.  Options for treatment residuals are provided below:

  • GAC – Spent Media Incinerated/Landfilled
  • Ion Exchange – Spent Media Incinerated/Landfilled
  • RO – Brine Sent to Sanitary Sewer or Landfilled

Future regulatory actions not under the Safe Drinking Water Act (SDWA) may have a bearing on future disposal options.

PFAS Resources

The Update site
The Update is a monthly newsletter exclusively focused on U.S. water news, encompassing regulatory compliance and political developments.

PFAS Articles from The Update

RSS PFAS – The Update – AE2S
  • Proposed Rules for PFAS and Other Emerging Chemicals of Concern
    The U.S. Environmental Protection Agency (USEPA) announced the latest efforts to protect communities and the environment from the health risks posed by certain per- and polyfluoroalkyl substances (PFAS). PFAS are long-lasting chemicals that break down very slowly over time, and they have been used in many different consumer, commercial, and industrial products. USEPA proposes two […]
  • New Year Brings New PFAS Regulations
    The new year ushered in a slew of new regulations on “forever chemicals” in states, as well as the anticipated finalization of the proposed drinking water regulation at the Federal level. Safe Drinking Water Act Standards for PFAS U.S. Environmental Protection Agency (USEPA) intends to finalize new drinking water standards for Per- and Polyfluoroalkyl Substances […]
  • Rule Finalized to Require Enhanced PFAS Reporting to Toxics Release Inventory
    The U.S. Environmental Protection Agency (USEPA) finalized a rule that improves reporting on per- and polyfluoroalkyl substances (PFAS) to the Toxics Release Inventory (TRI). USEPA eliminated an exemption that allowed facilities to avoid reporting information on PFAS when those chemicals were used in small concentrations. The so-called “forever chemicals” are used at low concentrations in […]
  • USGS Study Detects PFAS Contamination in 45% of Tap Water
    A new U.S. Geological Survey study found at least 45% of the tap water in the United States is contaminated with one or more types of per- and polyfluorinated alkyl substances (PFAS). The study reports samples from more than 700 public and private water systems for 32 PFAS compounds. The data is the result of […]
  • USEPA Releases Results of Nationwide Monitoring for 30 Chemicals
    The U.S. Environmental Protection Agency (USEPA) released the first set of data collected under the fifth Unregulated Contaminant Monitoring Rule (UCMR 5). The new data is the initial step towards improving USEPA’s understanding of the levels and frequency that 29 PFAS and lithium are found in the nation’s drinking water systems. The initial monitoring represents sampling from […]
  • Study Identifies Urgent Need for PFAS Prevention and Affordable Cleanup Options
    A recently published report serves as a wake-up call for the need for a comprehensive solution to per- and poly-fluoroalkyl substances (PFAS) pollution. The Minnesota Pollution Control Agency (MPCA) report emphasizes the importance of prevention to safeguard the environment and public health. PFAS enters wastewater through various channels, including industrial processes, the use and disposal […]
Drinking Water Practice - AE2S
Nate Weisenburger, PE, P Eng, ENV-SP
(406) 268-0626